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Tollens试剂等弱氧化剂与醛酮反应的研究
引用本文:王怀亮,李丹.Tollens试剂等弱氧化剂与醛酮反应的研究[J].山西师范大学学报,1988(2).
作者姓名:王怀亮  李丹
作者单位:山西师大化学系,山西师大化学系
摘    要:本文研究了乙醛、环己酮、3—戊酮、丙酮对 Tollens 等试剂的反应,得出环己酮,3—戊酮能被 Tollens 等试剂氧化,反应速率为乙醛>环己酮>3—戊酮>丙酮。从而对酮不能被 Tollens 试剂氧化的传统结论提出置疑,并对实验结果作出解释。

关 键 词:醛酮  氧化反应  Tollens  试剂

REACTIONS OF ALDEHYDER RETONES WITH OXIDITIVE REAGENTS SUCH AS TOLLENS REAGENT
Wang Huailiang Li Dan.REACTIONS OF ALDEHYDER RETONES WITH OXIDITIVE REAGENTS SUCH AS TOLLENS REAGENT[J].Journal of Shanxi Teachers University,1988(2).
Authors:Wang Huailiang Li Dan
Institution:Wang Huailiang Li Dan
Abstract:After the observation of the reactions of acetaldehyde, cyclohexanone,3-pentanone and acetone with Tollens reagent,etc,it is found that cyceohexanone,3-pentanone can be oxidised with Tollens reagent, etc,and their reaction rates are as follows: acetaldehyde>cyclohexanone >3-pent-anone>>acetone.As a result,the often held conclusion that Retones can,not be oxidised with Tollens Reagent is called into question. The result5 of the experiment is also analysed.
Keywords:aldehydes Retones oxiditive reaction Tollens reagent
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