| 混合溶剂中AgCl、AgBrO_3溶度积的SPT计算 |
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| 引用本文： | 宋文煜,王风云. 混合溶剂中AgCl、AgBrO_3溶度积的SPT计算[J]. 南京理工大学学报(自然科学版), 1992, 0(1) |
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| 作者姓名： | 宋文煜 王风云 |
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| 作者单位： | 化工学院(宋文煜)，化工学院(王风云) |
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| 摘 要： | 以AgCl.AgBrO_2在一系列浓度的MeOH—H_2O,EtOH—H_2O,n—PrOH—H_2O,Me_2CO—H_2O及DMSO—H_2O混合溶剂中的离解平衡为研究对象,用定标粒子理论计算了这些难溶盐的浓度积,计算结果与文献值吻合很好。
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| 关 键 词： | 混合 溶剂 溶度积 溶解自由能 定标粒子理论 |
A Calculation of Solubility Product for AgCl and AgBrO_3 in Aqueous Mixtures According to the Scaled Particle Theory. |
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| Song Wenyu Chemical Engineering School et al. A Calculation of Solubility Product for AgCl and AgBrO_3 in Aqueous Mixtures According to the Scaled Particle Theory.[J]. Journal of Nanjing University of Science and Technology(Nature Science), 1992, 0(1) |
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| Authors: | Song Wenyu Chemical Engineering School et al |
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| Affiliation: | Song Wenyu Chemical Engineering School et al |
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| Abstract: | By improving the fomula of the ionization equilibrium and thecalculation process developed in the previous works, we took the ionization e-quilibrium of AgCl and AgBrO_3 in a series of MeOH - H_2O, EtOH - H_2O,PrOH - H_2O, acetone - H_2O and DMSO - H_2O mixtures as the examples inthis article, and calculated the solubility product constants of the slightly solu-ble salts. The obtained values are in good accoedance with those from litera-tures. |
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| Keywords: | intermix solvents solubility product free melting energy scaled particle theory |
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