| 不活泼芳胺异硫氰酸酯的合成研究 |
| |
| 引用本文： | 蒋胜前,王周玉,蒋珍菊,陈万义,李建惠. 不活泼芳胺异硫氰酸酯的合成研究[J]. 四川师范大学学报(自然科学版), 2011, 34(3): 388-391. DOI: 10.3969/j.issn.1001-8395.2011.03.023 |
| |
| 作者姓名： | 蒋胜前 王周玉 蒋珍菊 陈万义 李建惠 |
| |
| 作者单位： | 西华大学制药工程系,四川成都,610039 |
| |
| 基金项目： | 四川省青年基金(2010JQ0048); 四川省教育厅自然科学重点项目(09ZA110)基金资助项目 |
| |
| 摘 要： | 以不活泼芳胺、二硫化碳(CS2)、三乙烯二胺(DABCO)、双(三氯甲基)碳酸酯(BTC)为原料合成不活泼芳胺异硫氰酸酯,对合成条件进行了研究,在最优的条件下合成了7个不活泼芳胺异硫氰酸酯,收率高达95%,并利用红外、核磁对其结构进行了表征.
|
| 关 键 词： | 异硫氰酸酯 不活泼芳胺 三乙烯二胺 双(三氯甲基)碳酸酯 |
The Study on Synthesis Inactive Aromatic Amine Isothiocyanates |
| |
| JIANG Sheng-qian,WANG Zhou-yu,JIANG Zhen-ju,CHEN Wan-yi,LI Jian-hui. The Study on Synthesis Inactive Aromatic Amine Isothiocyanates[J]. Journal of Sichuan Normal University(Natural Science), 2011, 34(3): 388-391. DOI: 10.3969/j.issn.1001-8395.2011.03.023 |
| |
| Authors: | JIANG Sheng-qian WANG Zhou-yu JIANG Zhen-ju CHEN Wan-yi LI Jian-hui |
| |
| Affiliation: | JIANG Sheng-qian,WANG Zhou-yu,JIANG Zhen-ju,CHEN Wan-yi,LI Jian-hui(Department of Pharmaceutics Engineering,Xihua University,Chengdu 610039,Sichuan) |
| |
| Abstract: | Inactive aromatic amine isothiocyanates were synthesized with the inactive arylamines,carbon disulfide,1,4-diazabicyclo-octane,bis(trichloromethyl) carbonate.The reaction conditions were studied and seven inactive aromatic amine isothiocyanates were synthesized under the optimal conditions.The yield was up to 95%.Meanwhile,the structures were characterized by the infrared spectrum and NMR spectrum. |
| |
| Keywords: | isothiocyanate inactive aromatic amine 1 4-diazabicyclo-octane bis(trichloromethyl) carbonate |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
