| 系列Con+配合物中奇妙的氢键网络 |
| |
| 引用本文： | 牛淑云,金晶,范洪涛.系列Con+配合物中奇妙的氢键网络[J].辽宁师范大学学报(自然科学版),2002,25(4):398-401. |
| |
| 作者姓名： | 牛淑云 金晶 范洪涛 |
| |
| 作者单位： | 辽宁师范大学,化学系,辽宁,大连,116029 |
| |
| 基金项目： | 国家自然科学基金资助项目(20071016) |
| |
| 摘 要： | 采用水热合成反应, 合成了系列含有多种氢键网络的Con+ 配位化合物 Co(C4H13N3)2]2*C6H2(COO)4]3/2*8H2O (1); Co(phen)(H2O)3]*C6H2(COO)4]1/2*H2O (2); Co(C3H4N2)6](NO3)2 (3).对各化合物的单晶进行了X光衍射分析,结果表明,在每个化合物中存在多种氢键,使化合物晶体构成了无限伸延的三维网络结构,形成了广义上的超分子.经对比研究讨论了各化合物中不同类型氢键及其在结构中的作用.
|
| 关 键 词： | 晶体结构 氢键网络 钴配合物 |
| 文章编号： | 1000-1735(2002)04-0398-04 |
| 修稿时间： | 2002年10月20 |
Wonderful Hydrogen Bonded Network in a Series of Con+ Complex |
| |
| NIU Shu yun,JIN Jing,FAN Hong tao.Wonderful Hydrogen Bonded Network in a Series of Con+ Complex[J].Journal of Liaoning Normal University(Natural Science Edition),2002,25(4):398-401. |
| |
| Authors: | NIU Shu yun JIN Jing FAN Hong tao |
| |
| Abstract: | A series of the Co n+ complex with many kinds of hydrogen bond were synthesized .The X ray diffraction of the crystals of these compounds was analyzed. The results show that there are many kinds of hydrogen bond and the crystals have infinite three dimensional network. The generalized supermolecular is formed. The various kinds of hydrogen bond in the compounds and their effect on the crystal structure are discussed. |
| |
| Keywords: | Co n+ complex crystal structure hydrogen bonded network |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
