| 以羧酸为酰化试剂的Friedel-Crafts酰基化反应 |
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| 引用本文： | 白国义,韩捷,闫喜龙. 以羧酸为酰化试剂的Friedel-Crafts酰基化反应[J]. 河北大学学报(自然科学版), 2011, 31(6): 658-667 |
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| 作者姓名： | 白国义 韩捷 闫喜龙 |
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| 作者单位： | 1. 河北大学化学与环境科学学院,药物化学与分子诊断教育部重点实验室,河北保定071002
2. 天津大学化工学院,天津,300072 |
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| 基金项目： | 国家自然科学基金资助项目(20806018); 河北省自然科学基金资助项目(B2011201017); 河北省教育厅自然科学研究重点计划资助项目(ZD200910) |
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| 摘 要： | 分别介绍了以脂肪族和芳香族羧酸为酰化试剂的Friedel-Crafts酰基化反应,重点比较了各种催化剂的优缺点,指出以羧酸为酰化试剂、以环境友好的固体酸为催化剂的Friedel-Crafts酰基化反应是今后芳香酮类化合物合成的发展方向.
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| 关 键 词： | 羧酸 Friedel-Crafts酰基化反应 芳香酮类化合物 固体酸催化剂 |
Friedel-Crafts Acylation of Aromatic Compounds with Carboxylic Acids as Acylating Agents |
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| BAI Guo-yi,HAN Jie,YAN Xi-long. Friedel-Crafts Acylation of Aromatic Compounds with Carboxylic Acids as Acylating Agents[J]. Journal of Hebei University (Natural Science Edition), 2011, 31(6): 658-667 |
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| Authors: | BAI Guo-yi HAN Jie YAN Xi-long |
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| Affiliation: | BAI Guo-yi1,HAN Jie1,YAN Xi-long2 (1.Key Laboratory of Medicinal Chemistry and Molecular Diagnosis of Ministry of Education,College of Chemistry and Environmental Science,Hebei University,Baoding 071002,China,2.School of Chemical Engineering and Technology,Tianjin University,Tianjin 300072,China) |
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| Abstract: | Friedel-Crafts acylation with both aliphatic and aromatic carboxylic acids as acylating agents are reviewed and the characters of different catalysts are emphatically compared.Friedel-Crafts acylation with carboxylic acids as acylating agents and solid acids as catalysts are believed as the trend for the green synthesis of aromatic ketones. |
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| Keywords: | carboxylic acids Friedel-Crafts acylation aromatic ketones solid acids catalysts |
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