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SO4^2-/TiO2催化马来酸酐均聚反应研究
引用本文:李建华 吴东辉. SO4^2-/TiO2催化马来酸酐均聚反应研究[J]. 南通大学学报(自然科学版), 2007, 6(2): 44-46
作者姓名:李建华 吴东辉
作者单位:南通大学化学化工学院 江苏南通226007
摘    要:以N,N-二甲基甲酰胺为溶剂、SO42-/TiO2作催化剂,在加热回流条件下催化马来酸酐均聚反应.分别用XRD对催化剂、FT-IR对均聚产物进行了表征.实验结果显示:SO24-/TiO2对马来酸酐催化反应具有很高的催化活性.文章对催化机理进行了初步分析.

关 键 词:马来酸酐  聚合  SO_4~(2-)/TiO_2  机理
文章编号:1673-2340(2007)02-0044-03
修稿时间:2006-10-13

Study on Polymerization of Maleic Anhydride Catalyzed by SO4^2-/TiO2
LI Jian-hua, WU Dong-hui. Study on Polymerization of Maleic Anhydride Catalyzed by SO4^2-/TiO2[J]. Journal of Nantong University (Natural Science Edition), 2007, 6(2): 44-46
Authors:LI Jian-hua   WU Dong-hui
Affiliation:School of Chemistry and Chemical Engineering, Nantong University, Nantong 226007, China
Abstract:Polymerization of maleic anhydride was catalyzed by SO42-/TiO2 using N,N-dimethyl formamide as solvent under the refluxing condition.The catalysts were characterized by XRD,and products were characterized by FT-IR method respectively.Experiment results showed that SO42-/TiO2 had high catalytic activity when catalyzing polymerization of maleic anhydride.In addition,the catalytic mechanism was studied primarily.
Keywords:maleic anhydride  polymerization  SO42-/TiO2  mechanism
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