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化学热力学关系式中反应进度的引入
引用本文:王艳芝,谢丹阳,佟琦.化学热力学关系式中反应进度的引入[J].燕山大学学报,2003,27(2):185-188.
作者姓名:王艳芝  谢丹阳  佟琦
作者单位:燕山大学环境与化学工程系,秦皇岛 066004
摘    要:反应进度概念(ζ)已引入到反应热的计算、化学平衡及反应速率的定义式中,但ζ没有普遍地被引入其它热力学关系式。因此,经过具体推证,将ζ系统地引入了热力学基本方程、对应系数关系式、化学平衡条件、自发方向的判据和平衡移动原理关系式中。并且推出化学亲和势的其它表示形式,从而使主要公式的应用更加规范。

关 键 词:化学热力学  反应进度  关系式  反应热  化学平衡  反应速率  化学亲和势
修稿时间:2002年2月25日

Introducing Extent of Reaction in Chemical Thermodynamics' Relations
,.Introducing Extent of Reaction in Chemical Thermodynamics'''' Relations[J].Journal of Yanshan University,2003,27(2):185-188.
Authors:,,
Institution:(Wang Yanzhi),(Xie Danyang),(Tong Qi),(The Department of environment and Chemical Engineering,Yanshan University,Qinhuangdao 066004)
Abstract:Extent of reaction has been introduced in teaching and researching, but it hasn't universally been drawn into the other relations of Chemical Thermodynamics but for calculations in Thermo-chemistry and definition of reaction' rate. Thus, it has been concretely reasoned to draw into the basic relations of Chemical Thermodynamics, corresponding coefficient, the criterion of the chemical equilibrium and it of the spontaneous reactions' orientation, shifting equilibrium principles, and the other forms of affinity' definition have been out. This made reasoning relations more standard.
Keywords:extent of reaction  chemical thermodynamics  relations  
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