| 机械化学条件下的无溶剂多组分反应合成2,4-二苯基喹啉 |
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| 引用本文： | 谭亚军,王方建,李金瑞,马景涛,张泽. 机械化学条件下的无溶剂多组分反应合成2,4-二苯基喹啉[J]. 安徽工程科技学院学报：自然科学版, 2014, 0(3): 20-23 |
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| 作者姓名： | 谭亚军 王方建 李金瑞 马景涛 张泽 |
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| 作者单位： | 安徽工程大学 生物与化学工程学院,安徽 芜湖,241000 |
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| 基金项目： | 国家自然科学基金资助项目 |
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| 摘 要： | 在机械化学球磨条件下发展出一种快捷合成2,4-二苯基喹啉的高效与环境友好的新方法.该方法反应时间短、效率高,无须分离原位生成的中间体,使用的三氯化铁催化剂安全价廉且反应后处理简单.这些优点使得该一锅无溶剂方法有望替代传统方法来实现绿色合成此类化合物.
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| 关 键 词： | 苯乙炔 氯化铁 喹啉 机械化学 |
Preparation of quinoline derivatives under mechanic chemistry |
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| TAN Ya-jun,WANG Fang-jian,LI Jin-rui,MA Jing-tao,ZHANG Ze. Preparation of quinoline derivatives under mechanic chemistry[J]. Journal of Anhui University of Technology and Science, 2014, 0(3): 20-23 |
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| Authors: | TAN Ya-jun WANG Fang-jian LI Jin-rui MA Jing-tao ZHANG Ze |
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| Affiliation: | (Coll. of Bioch. Engn.,Anhui Polytechnic University, Wuhu 241000, China) |
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| Abstract: | A highly efficient and environmentally friendly method has been developed for facile synthesis of 2, 4-diphenylquinolines under mechanochemical ball-milling conditions. The advantages of short reac- tion time, high efficiency, no separation of in situ generated intermediate, using cheap iron（ Ⅲ ） chloride as the catalyst, together with very simple work-up procedure, make this one-pot and solvent-free proto- col a green and powerful alternative to traditional methods for the synthesis of these kinds of com- pounds. |
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| Keywords: | phenylacetylene iron (Ⅲ)chloride quinoline mechanochemistry |
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