| 铁的1,5,9-环十二碳三烯配合物合成及性质的研究 |
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| 引用本文： | 傅鹏飞,候益民,金斗满.铁的1,5,9-环十二碳三烯配合物合成及性质的研究[J].河南科学,1988(4). |
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| 作者姓名： | 傅鹏飞 候益民 金斗满 |
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| 作者单位： | 河南化学研究所
(傅鹏飞，候益民)，河南化学研究所(金斗满) |
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| 摘 要： | 摘要本文研究了Fe(CO)_5与all-trans-CDT(Cyclododecantrine)的热反应,分离得到了一种高产率的all-trans-CDT配合物,此配合物通过IR.NMR和MS谱研究确定为(CDT)Fe(CO)_3],其中1,5,9-all-tran-CDT中有二个非共轭烯键参与了配合,而另一个保持自由烯键.且研究了配合物(CDT)Fe(CO)_3]与pph_3和Br_2的反应.
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| 关 键 词： | Fe(CO)_5 all-trans-CDT 配位键 pph_3 Br_2 |
A STUDY ON THE SYNTHESIS AND PROPERTIES OF 1, 5, 9-ALL-TRANS-CYCLODODECTRIENE IRON COMPLEX |
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| Fu Pengfei, Hou Yimin, Jin Douman.A STUDY ON THE SYNTHESIS AND PROPERTIES OF 1, 5, 9-ALL-TRANS-CYCLODODECTRIENE IRON COMPLEX[J].Henan Science,1988(4). |
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| Authors: | Fu Pengfei Hou Yimin Jin Douman |
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| Abstract: | By the heat reaction of Fe(CO)_5 With all-trans-CDT, a new kind of iron CDT Complex, Fe (CDT)(CO)_3. Was isolated. The bond mode of the complex was deduced through IR, NMR and MS spectra. The reaction of (CDT) Fe (CO)_2 with Br_2 and pph_3 was investigated. |
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| Keywords: | Fe(CO)_5 all-trans-CDT Coordinate bond Pph_3 Br_2 |
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