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无机载体试剂和季铵盐相转移催化剂在邻苯二甲酰亚胺N—烃化反应中的应用
引用本文:孙兴华,金信高. 无机载体试剂和季铵盐相转移催化剂在邻苯二甲酰亚胺N—烃化反应中的应用[J]. 淮北煤炭师范学院学报(自然科学版), 1997, 0(1)
作者姓名:孙兴华  金信高
摘    要:本文研究了无机载体试剂K2CO3/Al2O3、KOH/Al2O3、KF/Al2O3、K2CO3/KOH/Al2O3K2CO3/KF/Al2O3及季铰盐相转移催化剂TBAB在邻苯二甲酸亚胺N—烃化反应中的应用.结果表明,邻苯二甲酸亚胺的N—烃化反应可以在上述试剂的作用下顺利地进行,且该反应具有收率高,后处理简单,无机载体可以回收再用等优点.

关 键 词:无机载体试剂  季铵盐  相转移催化PTC  邻苯二甲酰亚胺  N—烃化反应

The Application of Inorganic Supported Reagent and Quaternary Ammonium Salt Phase Tracsfer Catalyst in the N-alkylation of Phthalimide
Sun Xinhua, Jin Xingao. The Application of Inorganic Supported Reagent and Quaternary Ammonium Salt Phase Tracsfer Catalyst in the N-alkylation of Phthalimide[J]. Journal of Huaibei Coal Industry Teachers College(Natural Science edition), 1997, 0(1)
Authors:Sun Xinhua   Jin Xingao
Affiliation:Department of Chemistry
Abstract:In the paper,we study the application of inorganic supported reagent K2CO3/Al2O3.KOH/Al2O3. AF/Al2O3. K2CO2/KOH/Al2O3. K2CO3/KF/Al2O3 and quaternary ammonium salt phase transfer catalyst tetrabutylammonium bromide (TBAB) in the N - alkylation of phthalimide show that the N - aikylation of phthalimide is easily to carry out the in the above condition and the reaction has advantage of the good yield,simple procedure and reused inorganic support with no less reativity
Keywords:Inorganic supported reagent quaternary ammonium salt Phase tranffer catalyst (PTC) phthalimide N-albylation
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