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6-溴-1,3-苯并二恶茂-4-甲醛的合成
引用本文:敖波,彭强,赵为,杨占坤,蔡雅棠,朱家理,谢明贵. 6-溴-1,3-苯并二恶茂-4-甲醛的合成[J]. 四川大学学报(自然科学版), 2000, 37(3): 474-476
作者姓名:敖波  彭强  赵为  杨占坤  蔡雅棠  朱家理  谢明贵
作者单位:1. 四川大学化学学院,成都610064
2. 自贡师范专科学校,自贡643000
摘    要:

关 键 词:溴代邻位胡椒醛 合成 高血压药物 中国体
文章编号:0490-6756(2000)03-0474-03

SYNTHESIS OF 6-BROMO- 1 , 3-BENZODIOXOLE- 4-CARBONALDEHYDE
Ao bo,PENG Qiang,ZHAO Wei,YANG Zhan-kui,CAI Ya-tang,ZHU Jia-li,XIE Ming-Gui. SYNTHESIS OF 6-BROMO- 1 , 3-BENZODIOXOLE- 4-CARBONALDEHYDE[J]. Journal of Sichuan University (Natural Science Edition), 2000, 37(3): 474-476
Authors:Ao bo  PENG Qiang  ZHAO Wei  YANG Zhan-kui  CAI Ya-tang  ZHU Jia-li  XIE Ming-Gui
Abstract:The 6-bromo- 1, 3- benzodiozole- 4- carbonaldehyde was synthesized by using 2- hydroxy-3-methoxy benzaldehyde as an original reactant, through three steps of bromination, demethylation and methylenation. The title compound was identified by elemental analysis. IR, 1HNMR and MS. The melting point was 113-114℃ determined with macroscope melting instrument and was 113.8C determined with DSC.
Keywords:6-bromo- 1  3-benzodiozole-4-carbonaldehyde  synthesis  methylenation
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