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低浓乙酸的乙酸/水混合物分离
引用本文:刘庆林,苏玉忠,张志炳. 低浓乙酸的乙酸/水混合物分离[J]. 厦门大学学报(自然科学版), 2001, 40(5): 1078-1082
作者姓名:刘庆林  苏玉忠  张志炳
作者单位:1. 厦门大学化工系,
2. 南京大学化工系,
基金项目:福建省自然科学基金(F00022)和江苏省自然科学基金(BK99027)资助项目
摘    要:实验和模拟计算考察了低浓乙酸的乙酸/水混合物精馏特性,如体系物性和操作参数对精馏的影响。在较低乙酸浓度范围内,进一步精制乙酸,采用精馏方法所需理论级数大大增加。模拟计算表明,通过精馏-膜集成过程制备无水乙酸可望成为一种有应用前景的分离技术。

关 键 词:精馏 乙酸/水 憎水膜 无水乙酸 分离技术 膜集成过程 体系物性
文章编号:0438-0479(2001)05-1078-05
修稿时间:2000-08-29

Separation of Acetic Acid/Water Mixture under Dilute Acetic Acid
LIU Qing lin ,SU Yu zhong ,ZHANG Zhi bing. Separation of Acetic Acid/Water Mixture under Dilute Acetic Acid[J]. Journal of Xiamen University(Natural Science), 2001, 40(5): 1078-1082
Authors:LIU Qing lin   SU Yu zhong   ZHANG Zhi bing
Affiliation:LIU Qing lin 1,SU Yu zhong 1,ZHANG Zhi bing 2
Abstract:Separation of acetic acid/water mixture over dilute acetic acid by distillation was conducted, and the effects of several variables such as surface tension, pro duct purity, and reflux ratio on the theoretical stages in the column were studi ed. Further refining of acetic acid at a low concentration range wouled bring a bout a great increase in theoretical stages for distillation. It was found that distillation coupled pervaporation could be an alternative for acetic acid remo val from acetic acid/water mixture.
Keywords:distillation  acetic acid/water  hydrophobic membrane
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