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甲亚胺液晶共聚醚的合成及研究(Ⅳ)
引用本文:裴梅山,孙大岩,张代平. 甲亚胺液晶共聚醚的合成及研究(Ⅳ)[J]. 济南大学学报(自然科学版), 1996, 0(1)
作者姓名:裴梅山  孙大岩  张代平
作者单位:山东建材学院应用化学系
摘    要:用个晶基和柔性更好的非个晶基共聚的方法合成高分子液晶,通过热台偏光显微镜、DSC和X-光衍射仪对所合成的共聚物进行了结构和相态表征,讨论了共聚物组成对共聚物相变温度和相态的影响,确定了共聚物要呈现液晶态,允许非介晶组份在其组成中的最高含量。

关 键 词:甲亚胺液晶共聚醚;偏光显微镜;非介晶组分

SYNTHESES AND STUDIES OF LIQUID CRYSTALLINE COPOLYAZOMETHINEETHERS
Pei Meishan, Sun Dayan, Zhang Daiping. SYNTHESES AND STUDIES OF LIQUID CRYSTALLINE COPOLYAZOMETHINEETHERS[J]. Journal of Jinan University(Science & Technology), 1996, 0(1)
Authors:Pei Meishan   Sun Dayan   Zhang Daiping
Abstract:A series of main chain liquid crystalline coPOlymers is reported. Themesomorphous properties are examined by visual observation of optical POlarizing microscope,DSC and X-ray difftaction. It was found that all thermotropic liquid crystalline copolymers arenematic mesophase,and that copolymeritalion depresses crystallization transition temperatures andliquid crystalline transitions are weight-averaged over those of the parent homopolymers. Themaximum mole fractions of non-mesogenic units needed for apperance of melt anisotropy areabtained.
Keywords:liquid crystalline copolyazomethineethers  optical polarizing microscope  non mesogemic units.
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