| 在电场条件下NaCl熔体微观结构的研究 |
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| 引用本文： | 何杰,张明杰,王洪宽.在电场条件下NaCl熔体微观结构的研究[J].东北大学学报(自然科学版),1995(2). |
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| 作者姓名： | 何杰 张明杰 王洪宽 |
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| 作者单位： | 东北大学，辽宁省轻工业学校 |
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| 摘 要： | 采用ＭＣ法研究了ＮａＣｌ熔体在电场作用下的微观结构．结果表明，在电极表面存在着完全不同于水溶液的双电层结构，其第一配位层为整齐排布的Ｃｌ－离子，第二配位层为间隙排列的Ｎａ＋离子，而在距电极大于２（Ｒ＋＋Ｒ－）的熔体内部仍符合Ｂｏｌｔｚｍａｎｎ分布．
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| 关 键 词： | 双电层，熔体结构，MonteCarlo法 |
On the Microstructure of NaCl Melts under Action of Electric Field |
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| He Jie, Zhang Mingle, Wang Hongkuan.On the Microstructure of NaCl Melts under Action of Electric Field[J].Journal of Northeastern University(Natural Science),1995(2). |
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| Authors: | He Jie Zhang Mingle Wang Hongkuan |
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| Institution: | He Jie; Zhang Mingle; Wang Hongkuan |
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| Abstract: | Monte Carlo method was applied to the investigation on the microstructure of NaCI melts underthe action of electric field through computer simulation. It was found that there are electric double layers onthe surface of electrodes and they are significantly different froal those of aqueous solution. The first lay6rpresents that CI--ions are arranged in order,and the second layer presents that Na+ ions in gapped arrangement. However,the structures inside the melts at a distance greater than 2(R+ +R-- )from electrode surfaceare still in compliance with foltzmann distribution. |
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| Keywords: | electric double layer melt microstructure Monte Carlo method |
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