| 杯芳烃-硝基氯苯包络物的电化学行为研究 |
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| 引用本文： | 张霞,张清,赵迪思,罗川南,周长利. 杯芳烃-硝基氯苯包络物的电化学行为研究[J]. 济南大学学报(自然科学版), 2005, 19(1): 45-47 |
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| 作者姓名： | 张霞 张清 赵迪思 罗川南 周长利 |
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| 作者单位： | 1. 济南大学,化学化工学院,山东,济南,250022
2. 唐山学院,管理工程二系,河北,唐山,063000 |
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| 基金项目： | 山东省教育厅科技计划资助项目 (J0 2C0 7) |
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| 摘 要： | 研究了pH =5 .74的 0 .3mol·L-1KCl底液中杯芳烃与硝基氯苯包络物在汞电极上的极谱行为 ,测定了他们的包络比 ,用电流法测定了它们的包络常数 ,研究了温度对它们的影响 ,结果表明杯芳烃的结构对包络常数有影响 ,所形成的包络物在一定的温度范围内稳定。
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| 关 键 词： | 分析化学 杯芳烃 硝基氯苯 电化学 |
| 文章编号： | 1671-3559(2005)01-0045-03 |
| 修稿时间： | 2004-07-28 |
Electrochemical Behaviors of the Inclusion Complexes of Calix [n] arenas with Nitrochlorobenzene |
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| ZHANG Xia,ZHANG Qing,ZHAO Di-si,LUO Chuan-nan,ZHOU Chang-li. Electrochemical Behaviors of the Inclusion Complexes of Calix [n] arenas with Nitrochlorobenzene[J]. Journal of Jinan University(Science & Technology), 2005, 19(1): 45-47 |
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| Authors: | ZHANG Xia ZHANG Qing ZHAO Di-si LUO Chuan-nan ZHOU Chang-li |
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| Affiliation: | ZHANG Xia1,ZHANG Qing2,ZHAO Di-si1,LUO Chuan-nan1,ZHOU Chang-li1 |
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| Abstract: | The polarographical behaviors of calix[n]arenes with nitrochlorbenzene inclusion complexes were investigated on drop-mercury electrode in a solution of 0.3 mol/LKCl(pH=5.74).The moral ratio of host-guest was determined and the inclusion constants of host-gust were determined by electrochemical methods,the influences of temperature on the inclusion actions were also investigated.The results indicated that the inclusion constants were affected by the structure of calix[n]arenas and the inclusion complexes were steady in a certain range of temperature. |
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| Keywords: | analytical chemistry calix[n]arenas nitrochlorobenzne electrochemistry |
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