| ON THE CALCULATION OF MESOPORE SIZE DISTRIBUTION BY THE GAS ADSORPTION METHOD |
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| 作者单位： | Department of Textile Chemical Engineering陈晓立，Department of Textile Chemical Engineering张红浪，Department of Textile Chemical Engineering |
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| 摘 要： | Seeing that some commercial gas adsorption instrument still uses a too rough method for cal-culation of mesopore size distribution, we reviewed some practical methods of calculation so farproposed in the literature. We have found that most of these methods and many books have someincorrectness in the geometric factor Q_i used for the calculation of pore volume △V_i from corevolume △V_i~k. It has been proved that the correct expression for Q_i should be_i/(_i~k+1/2△t_i)]~2for cylindrical pores, _i,/(_i~k+1/2△t_i)for slit-shaped pores. On the basis of this correct Q_i,these methods were applied to the desorption isotherms. The results were compared and analyzed.
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ON THE CALCULATION OF MESOPORE SIZE DISTRIBUTION BY THE GAS ADSORPTION METHOD |
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| Authors: | Tong Husong Chen Xiaoli Zhang Honglang |
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| Institution: | Tong Husong,Chen Xiaoli,Zhang Honglang,Department of Textile Chemical Engineering |
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| Abstract: | |
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| Keywords: | porous material pore size distribution adsorption capillary condensation |
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