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THE ADHESIVE CAPACITY OF STARCH GRAFT COPOLYMERS TO POLYESTER/COTTON FIBER
作者单位:Zhu Zhifeng(Department of Chemistry,Wuhan University,Hubei,430072)Zhou Yongyuan Zhang Wengeng OuShiyan(Department of Textile Engineering,CTU)
摘    要:The advantages of using starch graft copolymers as warp sizes in textile were briefly discussed, and the factors of affecting adhesive capacity to the fiber were analysed. By using eerie ammonium nitrate as an initiator under nitrogen atomosphere, a number of vinyl and/or acrylic monomers such as acrylic acid, acrylamide, methyl acrylate, ethyl acrylate, butyl acrylate, hydroxyethyl acrylate, methyl methacrylate, butyl methacrylate, vinyl acetate and the combinations among them were graft copolymerized respectively onto granular corn starch in aqueous dispersion. The adhesive capacity of these starch graft copolymers to polyester/cotton fibers was evaluated by a slightly sized rovings according to V. K. Aggarwal's method which measures the breaking strength and elongation of the rovings impregnated with the size paste. The influences of the monomers and their combinations, the grafting technological processes and the pretreatment methods before graft copolymerization upon adhesive capacity have been dis


THE ADHESIVE CAPACITY OF STARCH GRAFT COPOLYMERS TO POLYESTER / COTTON FIBER
Zhu Zhifeng. THE ADHESIVE CAPACITY OF STARCH GRAFT COPOLYMERS TO POLYESTER / COTTON FIBER[J]. Journal of Donghua University, 1995, 0(1)
Authors:Zhu Zhifeng
Abstract:The advantages of using starch graft copolymers as warp sizes in textile were briefly discussed, and the factors of affecting adhesive capacity to the fiber were analysed. By using eerie ammonium nitrate as an initiator under nitrogen atomosphere, a number of vinyl and / or acrylic monomers such as acrylic acid, acrylamide, methyl acrylate, ethyl acrylate, butyl acrylate, hydroxyethyl acrylatc, methyl methacrylate, butyl methacrylate, vinyl acetate and the combinations among them were graft copolymcrized respectively onto granular corn starch in aqueous dispersion. The adhesive capacity of these starch graft copolymers to polyester / cotton fibers was evaluated by a slightly sized rovings according to V. K. Aggarwal's method which measures the breaking strength and elongation of the rovings impregnated with the size paste. The influences of the monomers and their combinations, the grafting technological processes and the pretrcatment methods before graft copolymerization upon adhesive capacity have been discussed in this paper. The results show that the factors above all have a marked influence upon the adhesive capacity of starch graft copolymers to polyester / cotton fibers.
Keywords:starch   mordified starch   size   graft   copolymerization   adhesive Capacity  
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