| 具有3维阳离子超分子框架结构的(4,4'-BipyH2)2(FeCl4)3·Cl的水热合成和晶体结构 |
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| 引用本文： | 陈文通,胡龙.具有3维阳离子超分子框架结构的(4,4'-BipyH2)2(FeCl4)3·Cl的水热合成和晶体结构[J].井冈山学院学报,2010,31(4). |
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| 作者姓名： | 陈文通 胡龙 |
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| 作者单位： | 井冈山大学化学化工学院,江西省配位化学重点实验室,江西,吉安,343009 |
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| 摘 要： | 通过水热反应合成了一种新的具有3维阳离子超分子框架结构的化合物(4,4'-BipyH2)2(FeCl4)3·Cl(1),并对该化合物进行了X-射线单品结构表征.该化合物具有孤立结构特征,在分子中含有4,4'-BipyH2,FeCl4和氯离子.它们通过氢键形成3维阳离子超分子框架结构.(FeCl4)-离子位于该超分子框架结构的空隙中.
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| 关 键 词： | 联吡啶 氯化物 晶体 水热 铁 |
HYDROTHERMAL SYNTHESIS AND CRYSTAL STRUCTURE OF (4,4'-BIPYH2)2(FECL4)3CL WITH A 3-D CATIONIC SUPRAMOLECULAR FRAMEWORK |
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| CHEN Wen-tong,HU Long.HYDROTHERMAL SYNTHESIS AND CRYSTAL STRUCTURE OF (4,4'-BIPYH2)2(FECL4)3CL WITH A 3-D CATIONIC SUPRAMOLECULAR FRAMEWORK[J].Journal of Jinggangshan University,2010,31(4). |
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| Authors: | CHEN Wen-tong HU Long |
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| Abstract: | A new compound with a three-dimensional cationic supramolecular framework, (4,4'-BipyH2)2(FeCl4)3Cl(1),has been synthesized via hydrothermal reaction and structurally characterized by single-crystal X-ray diffraction. The crystal structure analysis reveals that the title compound features an isolated structure, based on 4,4'-BipyH2 moieties, Cl- anions and an iron atom terminally bound by four chlorine atoms. The 4,4'-BipyH2 moieties, Cl- anions and (FeCl4)- anions are interconnected via hydrogen bonds to form a 3-D cationic supramolecular framework with some (FeCl4)- anions residing in the voids of the cationic supramolecular framework. |
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| Keywords: | Bipyridine chloride crystal hydrothermal iron |
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