Laser induced photoemission electron and the generation of high Rydberg states of atoms and molecules |
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Authors: | Li Wang Haiyang Li Jiling Bai Richang Lu |
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Affiliation: | (1) State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, 116023 Dalian, China |
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Abstract: | Laser induced photoemission electron was produced by directing 532 nm and/or 355 nm onto stainless steel plate on a time of flight mass spectrometer. Multiple charged ions and high Rydberg states of atoms or molecules were successfully generated by impacts of the photoemission electrons. The high Rydberg states (n ∼ 40–100) thus produced were separated from ions, produced by direct electron impact ionization, by a 3 V DC electric field and then ionized by a delayed pulsed HV electric field in a ZEKE-PFI manner. Relationship between generation/property of high Rydberg states of atoms/molecules and experimental conditions could be investigated. Relationship between the electron accelerating voltage and high Rydberg states of Ar was described. |
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Keywords: | photoemission electron multiple charged ions high Rydberg states |
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