| 求取连续一级反应速率常数的新方法 |
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| 引用本文： | 李可群.求取连续一级反应速率常数的新方法[J].实验科学与技术,2011,9(6):22-23,45. |
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| 作者姓名： | 李可群 |
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| 作者单位： | 同济大学化学系,上海,200092 |
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| 摘 要： | 提出了一种新的求取连续一级反应速率常数的简便方法,该原理和计算简单,无需编程,并能得到满意的结果。利用羰基氰化氯苯腙与巯基乙醇的连续一级反应体系的文献实验数据来验证文中公式,计算结果优于文献值。
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| 关 键 词： | 连续一级反应 速率常数 测定 迭代 |
A New Method for Obtaining Rate Constants of Consecutive First-order Reaction |
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| LI Ke-qun.A New Method for Obtaining Rate Constants of Consecutive First-order Reaction[J].Experiment Science & Technology,2011,9(6):22-23,45. |
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| Authors: | LI Ke-qun |
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| Institution: | LI Ke-qun (Department of Chemistry,Tongji University,Shanghai 200092,China) |
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| Abstract: | A new simple method for obtaining rate constants of consecutive first-order reaction was presented.This method works with simple principle and calculation,doesn＇t need programming,and can produce satisfactory results.The experimental data of consecutive first-order reaction of carbonyl cyanide 3-chlorophenylhydrazone with 2-mercaptoethanol was used for calculation,and the results are better than those of reference work. |
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| Keywords: | consecutive first-order reaction rate constant determination iteration |
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