| 铋试剂-1的硫-碳键断裂及其与二苄基锡的晶体结构研究 |
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| 引用本文： | 高洪芳,李凤,张如芬. 铋试剂-1的硫-碳键断裂及其与二苄基锡的晶体结构研究[J]. 聊城大学学报(自然科学版), 2004, 17(4): 13-15 |
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| 作者姓名： | 高洪芳 李凤 张如芬 |
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| 作者单位： | 聊城市第二中学,山东,聊城,252000;聊城大学,化学化工学院,山东,聊城,252059 |
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| 基金项目： | 国家自然科学基金资助课题(20271025) |
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| 摘 要： | 用二苄基二氯化锡与铋试剂-1反应,发生了碳-硫键的断裂,并形成了一种新的有机锡衍生物．用X-射线衍射测定了其晶体结构．
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| 关 键 词： | 二苄基二氯化锡 铋试剂-1 碳-硫键断裂 |
A Novel Cleavage S-C Bond of 2,5-Dimercapto-1,3,4-thiodiazole and Its two-Dimensional Crystal Structure with Dibenzyltin |
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| GAO Hong-fang,LI Feng,ZHANG Ru-Fen. A Novel Cleavage S-C Bond of 2,5-Dimercapto-1,3,4-thiodiazole and Its two-Dimensional Crystal Structure with Dibenzyltin[J]. JOURNAL OF LIAOCHENG UNIVERSITY (NATURAL SCIENCE, 2004, 17(4): 13-15 |
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| Authors: | GAO Hong-fang LI Feng ZHANG Ru-Fen |
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| Abstract: | A complex of dibenzyltin derivation was synthesized by the reaction of dibenzyltin dichloride with 2, 5-dimercapto-1, 3, 4-thiodiazole that one of carbon-sulfur bonds cleaved during the reaction. Its crystal structure was determined by X-ray diffraction, the weak interactions between tin and nitrogen atoms make the compound a dimmer and the coordination number of tin atom ambiguous. The high-atom interactions between adjacent sulfur atoms connected the dimers to form a two-dimensional plane. |
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| Keywords: | synthesis crystal structure two-dimension cleavage |
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