| 气液色谱法研究双—（o，o′—二正辛基二硫代磷酸酯）合镍（Ⅱ）与环戊酮加合反应的热力学性质 |
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| 引用本文： | 沈小平,项明长,朱多林,俞运鹏. 气液色谱法研究双—（o，o′—二正辛基二硫代磷酸酯）合镍（Ⅱ）与环戊酮加合反应的热力学性质[J]. 南京师大学报(自然科学版), 1996, 0(3) |
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| 作者姓名： | 沈小平 项明长 朱多林 俞运鹏 |
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| 作者单位： | 镇江师范专科学校化学系，镇江市教育委员会 |
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| 基金项目： | 江苏省教育委员会自然科学基金 |
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| 摘 要： | 用气液色谱法研究了双—（ｏ，ｏ′—二正辛基二硫代磷酸酯）合镍（Ⅱ）与环戊酮加合反应的热力学性质，测定了３３３．２～３６３．２Ｋ范围内加合反应的平衡常数，用最小二乘法求得反应的ΔＨ和ΔＳ．并描述了两者加合反应的平衡常数值的经验公式
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| 关 键 词： | 气液色谱法，酸碱加合反应，二烃基二硫代磷酸酯，环戊酮，热力学参数 |
Study on the Electrolytic Formation of AgO on the Silver Electrode in KOH Solution with In-Situ X-ray Diffration |
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| Abstract: | Cyclic voltammetry has been used to study the electrolytic formation of AgO at a silver electrode in aqeous KOH solutions.A range of concentrations of KOH and sweep rates have been used.The conditions under which an anodic peak appears on the negative-going sweep have been determined. The products AgO which formed at the reversed peak are in situ characterized with X-ray diffraction. |
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| Keywords: | In situ tests X-ray diffraction electrolytic formation AgO |
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