首页 | 本学科首页   官方微博 | 高级检索  
     检索      

乙基纤维素溶致液晶条带织构生长和松弛的动态过程
引用本文:董炎明.乙基纤维素溶致液晶条带织构生长和松弛的动态过程[J].厦门大学学报(自然科学版),1995,34(6):928-934.
作者姓名:董炎明
基金项目:国家教育委员会留学回国人员资助项目
摘    要:用偏光显微镜和透射光强分析技术,观察乙基纤维素-间甲酚和乙基纤维素-苯酚两个溶致液晶体系条带织构的生长和松弛的动态过程。结果表明条带织构生成的临界浓度高于液晶态形成的临界浓度,但低于两相并存向安全各向异性转变的浓度。

关 键 词:乙基纤维素  溶致液晶  条带织构  生长  松弛

Dynamic Process of Growth and Relaxation of Banded Texture for Lyotropic Liquid Crystalline Ethyl Cellulose
Dong Yanming.Dynamic Process of Growth and Relaxation of Banded Texture for Lyotropic Liquid Crystalline Ethyl Cellulose[J].Journal of Xiamen University(Natural Science),1995,34(6):928-934.
Authors:Dong Yanming
Institution:Dept.of Chem.
Abstract:Light microscopy and transmission optical analysis(TOA)technique wereused to observe the dynamic process for growth and relaxation of banded texture in two lyotropicliquid crystalline systems:ethyl cellulose(EC)-m-cresol and EC-phenol solutions. Banded texturepresented a fixed original width and remained unchanged during growing. A maximum peakappearing on TOA curve evidently divided the process into two stages:growth and relaxation ofbands. Relaxation slowed down as concentration rose. Growth became fastor while concentrationincreased,but in the case of lower concentration,slower growth was concealed by fasterrelaxation. The relaxation of bands accompanied a nematic to cholesteric mesophase transition.Furthermore, experiments showed the banded texture can occur in solution with two phasecoexistence of isotropic and anisotropic phase. The critical concentration of formation of bandedtexture was between c_1( normally defined )and c_2(transition from two phase to whollyanisotropic).
Keywords:thyl cellulose  Lyotropic liquid crystal  Banded texture  
本文献已被 CNKI 维普 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号