| 吡咯烷生物碱新手性合成子的合成 |
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| 引用本文： | 陈毅辉,黄培强.吡咯烷生物碱新手性合成子的合成[J].厦门大学学报(自然科学版),1995,34(5):772-777. |
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| 作者姓名： | 陈毅辉 黄培强 |
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| 基金项目： | 国家自然科学基金和国家教委霍英东教育基金 |
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| 摘 要： | 报道了从（Ｓ）－苹果酸出发，立体选择性地合成五个新吡咯烷生物碱手性合成子．观察到Ｃ＿４－位上保护的羟基对Ｃ＿５－位手性中心的形成具有良好的不对称诱导作用．
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| 关 键 词： | （S）－苹果酸，吡咯烷，手性合成子 |
Synthesis of Some New Chiral Synthons for Pyrroline Alkaloids Synthesis |
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| Chen Yihui, Huang Peiqiang, Fei Xiangsu, Ruan Yuanping.Synthesis of Some New Chiral Synthons for Pyrroline Alkaloids Synthesis[J].Journal of Xiamen University(Natural Science),1995,34(5):772-777. |
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| Authors: | Chen Yihui Huang Peiqiang Fei Xiangsu Ruan Yuanping |
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| Institution: | Dept.of Chem |
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| Abstract: | Starting from(S)-malic acid,five new chiral synthons useful for pyrrolidine.alkaloids synthesis were prepared stereos electively. Good asymmetric induction of protected C-4hydroxyl group over C-5 chiral center was observed. |
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| Keywords: | S)-Malic acid pyrrolidine Chiral synthon |
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