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PU与PVAc互穿网络聚合物的研究
引用本文:周宁琳,夏小仙.PU与PVAc互穿网络聚合物的研究[J].南京师大学报,1998,21(3):54-57.
作者姓名:周宁琳  夏小仙
作者单位:[1]南京师范大学化学系 [2]南京大学化学系
摘    要:研究了蓖麻油聚氨酯(PU)与聚醋酸乙烯酯(PVAc)在室温下生成的互穿网络聚合物(IPN)。通过FT-IR和凝胶含量的测定,说明此种IPN是接枝型IPN。考察了该IPN的各种组成对带锈铁板的附着力、柔韧性、冲击强度以及搭接剪切强度的影响。结果表明,当PU/PVAc=50/50(w/w,质量比)时,IPN的剪切强度最大,在此条件下合成的IPN涂料是带锈铁板的良好涂料。

关 键 词:IPN  蓖麻油  聚氨酯  涂料  聚醋酸乙烯酯

Studies on Castor Oil Polyurethane/Poly(vinyl acetate) Interpenetrating Polymer Networks
Abstract:The interpenetrating polymer networks(IPNS)obtained from castor oil polyurethane and Vinyl acetate monomer.The properties of this IPNS were Studied.Moreover,the sample of this graft IPN has been applied to coating when PU/PVAc is 50/50.The coating formed by PU/PVAc IPN on the iron plates without rust removal showed fairly good properties with respect to adhesion,impact strength,pliability and corrision resistivity.
Keywords:IPN  Castor oil polyurethane  vinyl acetate coating  property
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