| 己内酰胺与酰氯和酸酐反应的研究 |
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| 引用本文： | 张林丹,徐为群,蔡鲁青,蒋尚信,康群.己内酰胺与酰氯和酸酐反应的研究[J].东华大学学报(自然科学版),1992(1). |
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| 作者姓名： | 张林丹 徐为群 蔡鲁青 蒋尚信 康群 |
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| 作者单位： | 上海工程技术大学纺织学院，上海工程技术大学纺织学院，上海工程技术大学纺织学院，上海工程技术大学纺织学院，上海纺织科学研究院 |
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| 摘 要： | 己内酰胺在碱性介质中与酰氯反应,生成 N—酰基取代己内酰胺,后者也可以用相应的酸酐与己内酰胺在加热条件下制得。己内酰胺与等摩尔的邻苯二甲酰氯在碱性介质中的反应产物经水解后,和己内酰胺与等摩尔的邻苯二甲酸酐在加热条件下制得的产物不同。本文应用有机合成法并侧重用近代波谱解析阐明上述各步反应中的产物分子结构,澄清了文献中的分岐,合成了一些新化合物,提出上述有关反应的机理。
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| 关 键 词： | 乙内酰胺 酰化反应 邻苯二甲酰氯 邻苯二甲酸酐 阴离子聚合反应机理 波谱解析 |
THE STUDIES ON ACYLATlON REACTlON OF CAPROLACTAM WITH ACID CHLORIDE AND ACID ANHYDRIDE |
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| Zhang Lindan Xu Weiqun Cai Luqin Jiang Shangxin.THE STUDIES ON ACYLATlON REACTlON OF CAPROLACTAM WITH ACID CHLORIDE AND ACID ANHYDRIDE[J].Journal of Donghua University,1992(1). |
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| Authors: | Zhang Lindan Xu Weiqun Cai Luqin Jiang Shangxin |
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| Abstract: | Caprolactam reacted with acid chloride in basic medium to yield N-acyl caprolactam to
replace itself.The latter may be also prepared with corresponding acid anhydride and
caprolactam in heating.The hydrolytic product of the acyl derivative which was prepared by
caprolactam reacted with equimolar phthaloyl chloride in basic medium was different from
the compound which was prepared by caprolactam reacted with equimolar phthalic
anhydride in heating.In this article,we applied modern spectroscopic analysis rather than or-
ganic synthesis method to elucidate the correct structure of those products in above-men-
tioned reactions,thus clarifying the divergence of views in literature.Some new compounds
were formed through synthesis method and the mechanism of above rections was put
forward. |
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| Keywords: | caprolactam acylation phthaloyl chloride phthalic anhydride mechanism of anionic polymerization spectroscopic analysis |
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