| 镍-磷纳米非晶合金催化剂晶化过程及其C2H4+H2活性 |
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| 引用本文： | 张卫华,张春华,刘宗瑞,陈宝国,范以宁.镍-磷纳米非晶合金催化剂晶化过程及其C2H4+H2活性[J].内蒙古民族大学学报(自然科学版),2005,20(1):28-30. |
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| 作者姓名： | 张卫华 张春华 刘宗瑞 陈宝国 范以宁 |
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| 作者单位： | 1. 内蒙古民族大学,内蒙古,通辽,028043
2. 南京大学,化学学院,江苏,南京,210093 |
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| 基金项目： | 国家自然科学基金资助项目(29503018)和内蒙古民族大学基金资助项目(2002214) |
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| 摘 要： | 利用化学还原法制备了Ni893P10．7非晶态纳米合金催化剂，用电感藕合等离子体光谱法(ICP)、分析电子显微镜(TEM)、X-射线粉末衍射法(XRD)、BET表面积测试及X-光电子能谱(XPS)等手段对新鲜样品及经过热处理后的样品进行表征，并用微型催化反应装置评价其C2H4 H2催化活性，结果表明，非晶态Ni-P纳米合金具有比其晶态更高的催化活性。
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| 关 键 词： | Ni-P 非晶态合金纳米催化剂 晶化 C2H4＋H2 活性 |
| 文章编号： | 1671-0185(2005)01-0028-03 |
| 修稿时间： | 2004年10月24 |
The Crystallization Process and The C2H4+H2 Activity of Ni-P Nanosized Amporphous Alloy Catalyst |
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| ZHANG Wei-hua,ZHANG Chun-hua,LIU Zong-rui,CHEN Bao-guo,FAN Yi-ning.The Crystallization Process and The C2H4+H2 Activity of Ni-P Nanosized Amporphous Alloy Catalyst[J].Journal of Inner Mongolia University for the Nationalities(Natural Sciences),2005,20(1):28-30. |
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| Authors: | ZHANG Wei-hua ZHANG Chun-hua LIU Zong-rui CHEN Bao-guo FAN Yi-ning |
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| Institution: | ZHANG Wei-hua~1,ZHANG Chun-hua,LIU Zong-rui~1CHEN Bao-guo~1,FAN Yi-ning~2 |
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| Abstract: | The nanosized Ni-P Amorphous alloy particles has been prepared by chemical reduction.The fresh and the thermal treatment samples have been determined by inductively coupled plasma(ICP),transmission electron microscopy(TEM),X-ray diffraction(XRD),X-ray photoelectron spectroscopy(XPS) and surface area measurements.The catalytic activities of the catalysts in C_2H_4+H_2 were measured by a miniture catalytic reactor.The results indicate that the amorphous Ni-P alloy nanosized particles have higher catalytic activity than that of their crystalline state ones. |
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| Keywords: | Ni-P Nanosized amorphous alloy catalsts Crystllization C_2H_4+H_2 Activity |
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