| 四乙酰基六氮杂异伍兹烷的N-酰化反应研究 |
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| 引用本文： | 王艳飞,张艳维,吕会超,宋海香.四乙酰基六氮杂异伍兹烷的N-酰化反应研究[J].河南师范大学学报(自然科学版),2010,38(4). |
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| 作者姓名： | 王艳飞 张艳维 吕会超 宋海香 |
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| 作者单位： | 安阳工学院,化学与环境工程系,河南,安阳,455000 |
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| 基金项目： | 兵器科技预先研究项目 |
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| 摘 要： | 以四乙酰基六氮杂异伍兹烷(TAIW)和对氯苯甲酰氯为原料合成了四乙酰基-二(对氯苯甲酰基)六氮杂异伍兹烷,并通过红外光谱、核磁共振、质谱及元素分析确定了目标化合物的结构.讨论了反应介质、反应温度、反应时间、操作条件、催化剂对反应的影响,结果表明:DMF作反应介质,无水三氯化铝作为催化剂,在40℃下减压反应6h得到目标化合物,产物产率可达70.4%.
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| 关 键 词： | 四乙酰基六氮杂异伍兹烷 N-酰化 合成 |
N-acylation of Tetraacetylhexaazaisowurtzitane |
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| WANG Yan-fei,ZHANG Yan-wei,LV Hui-chao,SONG Hai-xiang.N-acylation of Tetraacetylhexaazaisowurtzitane[J].Journal of Henan Normal University(Natural Science),2010,38(4). |
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| Authors: | WANG Yan-fei ZHANG Yan-wei LV Hui-chao SONG Hai-xiang |
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| Abstract: | Tetraacety-bis(p-chlorobenzamido)hexaazaisowurtzitane is prepared through reaction between tetraacetylhexaazaisowurtzitane and p-Chlorobenzoic acid chloride.The structure of product has been determined by IR,1HNMR,MS and elemental analysis.The effect of reaction solvent,operation procedure,catalyst on yield and purity are discussed in order to find out the best synthesis condition.The optimum conditions are found as follows:Aluminum chloride anhydrous as catalyst,DMF as reaction medium,the reaction accomplished at 40 ℃ for 6 h in low pressure.The yield of target propounds is 70.4%. |
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| Keywords: | tetraacetylhexaazaisowurtzitane acylation synthesis |
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