| 硫代磷酸三(4-马来亚酰氨基苯)酯的合成 |
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| 引用本文： | 朱西挺,张跃华,张其平,雷武,陈勇,夏明珠,王风云.硫代磷酸三(4-马来亚酰氨基苯)酯的合成[J].南通大学学报(自然科学版),2010,9(1):60-63. |
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| 作者姓名： | 朱西挺 张跃华 张其平 雷武 陈勇 夏明珠 王风云 |
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| 作者单位： | 1. 南通大学化学化工学院,江苏,南通,226007
2. 南京理工大学工业化学研究所,江苏,南京,210094 |
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| 基金项目： | 南通大学自然科学基金项目(08Z014);;南通大学产学研合作项目(09C003) |
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| 摘 要： | 以对乙酰氨基苯酚和三氯硫磷为原料,经过酯化反应、水解反应得到硫代磷酸三(4-氨基苯)酯(TPTA),再以TPTA和马来酸酐为原料,经过酰胺化反应得到硫代磷酸三(4-马来亚酰氨基苯)酯(TPTM),总产率达到76.5%.以红外光谱、质谱及核磁共振谱对各产物的结构进行了表征,结果表明该法成功合成了目标产物.对TPTM紫外光谱进行了初步的研究,发现在204.5nm、280.0nm两处有吸收峰.
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| 关 键 词： | 硫代磷酸三（4一马来亚酰氨基苯）酯 酯化 水解 酰胺化 合成 |
Synthesis of Tris(4-maleylaminophenyl)thiophosphate |
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| Authors: | ZHU Xi-ting ZHANG Yue-hua ZHANG Qi-ping LEI Wu CHEN Yong XIA Ming-zhu WANG Feng-yun |
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| Institution: | 1. School of Chemistry and Chemical Engineering/a>;Nantong University/a>;Nantong 226007/a>;China/a>;2. Industrial Chemistry Institute/a>;Nanjing University of Science & Technology/a>;Nanjing 210094/a>;China |
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| Abstract: | Tris (4-aminophenyl)thiophosphate (TPTA) was synthesized from p-acetamindo phenol and phosphorus thiochloride through esterification and hydrolysis. Then Tris(4-maleoylaminophenyl)thiophosphate(TPTM) was synthesized from TPTA and maleic anhydride by amidation with the overall yield of 76.5%. IR, MS and NMR spectra were used to confirm the structure of TPTM and key intermediates. The ultraviolet-visible spectrum of TPTM was studied and there were two absorption peaks at 204.5 nm and 280.0 nm. |
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