| 4-甲基-1H-1,5-苯并二氮杂酮的形成机制及其四氢化物格氏反应的研究 |
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| 引用本文： | 王在军,薛仰琴,金声.4-甲基-1H-1,5-苯并二氮杂酮的形成机制及其四氢化物格氏反应的研究[J].北京大学学报(自然科学版),1992(6). |
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| 作者姓名： | 王在军 薛仰琴 金声 |
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| 作者单位： | 北京大学化学系
(王在军，薛仰琴)，北京大学化学系(金声) |
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| 摘 要： | 本文研究了4-甲基-1H-1,5-苯并二氮杂酮的形成机制及有关化合物的相互转化关系,澄清了文献上一些不一致的报导。在此基础上,改进了它的合成方法,并通过它的氢化产物的格氏反应,制备了一些新的化合物。
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| 关 键 词： | 1 5-苯并二氮杂酮 反应机制 1 3-σ键重排 格氏反应 |
Studies on the Mechanism of Formation of 1,5 -benzodiazepin-2-one and Grignard Reaction of Its Hydrogenation Product |
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| WANG Zaijun,XUE Yangqin,JIN Sheng.Studies on the Mechanism of Formation of 1,5 -benzodiazepin-2-one and Grignard Reaction of Its Hydrogenation Product[J].Acta Scientiarum Naturalium Universitatis Pekinensis,1992(6). |
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| Authors: | WANG Zaijun XUE Yangqin JIN Sheng |
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| Abstract: | The mechanism of formation and transformation relation of 4-methyl-lH-l, 5-benzodiazepin-2-one and related compounds are reported. Some inconsistent arguments in literatures have been cleared up. Based on it, the synthesis method has been improved. Several new compounds have been prepared by the Grignard reaction of its hydro-genation product. |
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| Keywords: | 1 5-Benzodiazepin-2-one Reaction mechanism 1 3-Sigmatropic reaction Grignard reaction |
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