| 聚硅氧烷乳液交联制备脱模剂的工艺条件研究 |
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| 引用本文： | 李建隆,苑光辉,王宇光,刘颖.聚硅氧烷乳液交联制备脱模剂的工艺条件研究[J].青岛化工学院学报(自然科学版),2013(6):589-592. |
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| 作者姓名： | 李建隆 苑光辉 王宇光 刘颖 |
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| 作者单位： | [1]青岛科技大学化工学院,山东青岛266042 [2]中国化学赛鼎宁波工程有限公司,浙江宁波315040 |
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| 基金项目： | 山东省自然科学基金资助项目（ZR2011BQ006）. |
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| 摘 要： | 以二甲基硅氧烷混合环体（DMC）为原料,利用乳液聚合法制得聚硅氧烷乳液,并用乙醇醇解甲基三氯硅烷所得的甲基三乙氧基硅烷进行乳液交联,最后以三甲基氯硅烷作为封端剂为其封端.研究了交联温度、交联反应时间、交联剂用量以及封端剂用量对乳液的影响,并确定了最适宜的反应条件,即交联温度为（60±5）℃,交联时间4h左右,交联剂用量为DMC质量的34％～46％,封端剂用量为DMC质量的5％～7％.
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| 关 键 词： | 二甲基硅氧烷混合环体（DMC） 乳液 交联 透光度 |
Preparation of Release Agent by Cross-linking of Polysiloxane Emulsion |
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| LI Jian-long,YUAN Guang-hui,WANG Yu-guang,LIU Ying.Preparation of Release Agent by Cross-linking of Polysiloxane Emulsion[J].Journal of Qingdao Institute of Chemical Technology(Natural Science Edition),2013(6):589-592. |
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| Authors: | LI Jian-long YUAN Guang-hui WANG Yu-guang LIU Ying |
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| Institution: | 1.College of Chemical Engineering,Qingdao University of Science and Technology, Qingdao 266042, China; 2.SEDIN NingBo Engineering Co.,LTD., Ningbo 315040,China;) |
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| Abstract: | Polysiloxane emulsion was prepared by emulsion polymerization using dimethylsiloxane hybrid ring body as raw material,Methyltrichlorosilane was alcoholysized by ethanol to prepare methyltriethoxysilane.The release agent was prepared by cross-linking reaction between emulsion and methyltriethoxysilane,and by end capping using trimethylchlorosilane as end capping agent.The influences of cross-linking temperature,cross-linking time,dosages of cross-linking and end capping agents on emulsion properties were studied.The optimum conditions were cross-linking temperature （60±5） ℃,cross-linking time 4 h,dosage of cross linking agent 34％-46％,dosage of end capping 5％-7％. |
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| Keywords: | dimethylsiloxane hybrid ring body （DMC） emulsion cross-linking transmittance |
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