| 邻菲咯啉对电沉积普鲁士蓝膜结构的影响 |
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| 引用本文： | 吴霞琴,张芬芬,盛春,施建成,姜远达,章宗穰.邻菲咯啉对电沉积普鲁士蓝膜结构的影响[J].上海师范大学学报(自然科学版),2004,33(4):56-60. |
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| 作者姓名： | 吴霞琴 张芬芬 盛春 施建成 姜远达 章宗穰 |
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| 作者单位： | 上海师范大学,生命与环境科学学院,上海,200234 |
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| 基金项目： | 上海市教委自然科学基金资助项目(01D04-2). |
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| 摘 要： | 应用循环伏安法在铂电极上进行了普鲁士蓝膜的电化学沉积，并对两种不同组成电解液中沉积的膜进行了扫描电镜、现场电化学拉曼光谱以及电化学阻抗谱的测量和表征．扫描电镜的测量结果表明，加入邻菲咯啉沉积的普鲁士蓝膜的形貌与不合邻菲咯啉的膜有明显不同，拉曼光谱测量证明了结构方面存在的差异，电化学阻抗谱则进一步验证了两类膜不同的电荷传递机制．
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| 关 键 词： | 普鲁士蓝 邻菲咯啉 循环伏安法 扫描电镜 拉曼光谱 电化学阻抗谱 |
| 文章编号： | 1000-5137(2004)04-0056-05 |
| 修稿时间： | 2004年6月20日 |
The effects of phenanthroline on the structure of prussian blue films by electrodeposited |
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| WU Xia-qin,ZHANG Fen-fen,SHENG Chun,SHI Jian-cheng,JIANG Yuan-da,ZHANG Zong-rang.The effects of phenanthroline on the structure of prussian blue films by electrodeposited[J].Journal of Shanghai Normal University(Natural Sciences),2004,33(4):56-60. |
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| Authors: | WU Xia-qin ZHANG Fen-fen SHENG Chun SHI Jian-cheng JIANG Yuan-da ZHANG Zong-rang |
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| Abstract: | Prussian blue (PB) films were electrodeposited in two types of electrolyte at platinum electrode by cyclic voltammetry. The corresponding CV plots, SEM, In-situ Raman Spectra and impedance spectra were measured. The results show that the morphology of the PB film with Phenathroline is different from that of the un cloped film. Moreover, the electron transfer process is also influenced by the structure of PB film and its thickness. |
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| Keywords: | prussian blue film phenanthroline cyclic voltammetry electron transfer process |
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