| Arrhenious反应律的动力学研究 |
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| 引用本文： | 吴玉喜,欧阳容百.Arrhenious反应律的动力学研究[J].南京大学学报(自然科学版),1990,26(4):613-617. |
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| 作者姓名： | 吴玉喜 欧阳容百 |
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| 作者单位： | 南京大学物理系，南京大学物理系 |
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| 摘 要： |
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| 关 键 词： | 化学反应速率 布朗粒子 非平衡态 |
A DYNAMICS STUDY OF THE ARRHENIOUS REACTION LAW |
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| Wu Yuxi Ouyang Rongbai.A DYNAMICS STUDY OF THE ARRHENIOUS REACTION LAW[J].Journal of Nanjing University: Nat Sci Ed,1990,26(4):613-617. |
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| Authors: | Wu Yuxi Ouyang Rongbai |
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| Institution: | Wu Yuxi Ouyang Rongbai Department of Physics |
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| Abstract: | In this paper,the Pokker-Planck dynamics equation is used for the Brownian particles system with viscosity,which is assumed to consist of chemical reactant molecules.The fa- mous Arrhenious reaction law is corrected in theory.The result shows that the rate of reac- tion is not only connected with the exponential of temperature,but also with the reciprocal coefficient of viscosity.It is more reasonable and consistent with experimental data than the Arrhenious velocity theory,molecular collision theory and absolute reaction rate theory. |
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| Keywords: | the rate of reaction Brownian particles Arrhenious reaction law nonequilibrium state |
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