| 胡椒醛缩异烟肼与钴,镍,铜和镉配合物的合成和表征 |
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| 引用本文： | 邓汉芹,王明雄.胡椒醛缩异烟肼与钴,镍,铜和镉配合物的合成和表征[J].湖北大学学报(自然科学版),1991,13(1):66-70. |
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| 作者姓名： | 邓汉芹 王明雄 |
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| 作者单位： | 湖北大学化学系
(邓汉芹，王明雄，杨桂春)，湖北大学实验中心(陈沛智) |
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| 摘 要： | 合成了以胡椒醛缩异烟肼(HPIN)为配体的四个新配合物:M(PIN)_2·nH_2OM=Co(Ⅱ)、Ni(Ⅱ)、Cu(Ⅱ)和Cd(Ⅱ),n=0.5～4]。通过元素分析、红外光谱、摩尔电导、紫外可见光谱、磁化率测定、~1H核磁共振谱和差热分析等研究了配合物的组成和性质。
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| 关 键 词： | 胡椒醛 异烟肼 HPIN 西佛碱络合物 |
SYNTHESIS AND CHARACTERIZATION OF THE COMPLEXES OF COB ALT, NICKEL, COPPER AND CADMIUM WITH PIPERONAL ISONICTINOYL HYDRAZONE |
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| Deng Hanqin Wang Mingxiong Yang Guichun Chen Peizhi.SYNTHESIS AND CHARACTERIZATION OF THE COMPLEXES OF COB ALT, NICKEL, COPPER AND CADMIUM WITH PIPERONAL ISONICTINOYL HYDRAZONE[J].Journal of Hubei University(Natural Science Edition),1991,13(1):66-70. |
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| Authors: | Deng Hanqin Wang Mingxiong Yang Guichun Chen Peizhi |
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| Institution: | Deng Hanqin Wang Mingxiong Yang Guichun Chen Peizhi
(Department of Chemistry) (Experimental Center) |
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| Abstract: | The synthesis and characterization of cobalt (II), nickel (II), copper (II) and cadmium(II) complexes with piperonal isonicotinoyl hydrazone(HPIN)are reported. Elemental analysis,molar conductance, magnetic measurements,electronic and I. R. spectra,and differential thermal analysis studies have been used to characterize the complezes. The analytical data show that the 1 : 2 complexes are M(PIN)2nH2OM=Co(lI) ,Ni(lI) ,Cu(Il). or Cd(Il) ,n=0. 5- 4]. A four coodinate geometry has been proposed for these complexes on the basis of magnetic and spectral measurements. |
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| Keywords: | Piperonal Isonicotinic hydrazide Schiff base complex Synthesis |
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