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Electronic Properties of Organic Semiconductors Based on Nonconjugated Polymers
作者姓名:A.N.Lachinov
作者单位:Institute of
摘    要:1 Results The paper presented review of experimental results on the charge transport study in the polymer materials,possessed charge instability.The base of these materials is noncojugated polyaromatic compounds.Characteristic feature these materials is a wide of band gap up to 4.3 eV and the value of first ionization potential about 6 eV.Electronic energetic parameters like these are typical for insulator materials.However it was established that there are not only hopping mechanism of charge transport possible but coherent too in such organic systems.Wide band gap organic material capable to transport charge carrier effectively under certain conditions and the same time conductivity can reach 105 (Ohm·cm)-1 value and current density up to 106 A/cm2 and more.Transformation to conducting phase may occur with different fields and influences,such as electric field,magnet field,pressure,temperature and others.These transformations are reversible as a rule.There is three main of the phenomena fields may be emphasize: electro-optical,switching,and electronic phenomena,including nanophenomena.Electro-optical phenomena are electroluminescence first of all1].Switching phenomena unites as following switching induced by electric field2],pressure3],magnet field4],boundary condition changing5],traps thermoionization6],particle irradiation7].Electronic phenomena which can observe in thin polyarylide films are as follow electron cold emission8],superconductivity9],charged induced nanomemory10],quantum dot generation11].

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