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自乳化环氧树脂成膜剂的制备
引用本文:马晓坤,冯旭,李峰,贾宏菲,杨春才.自乳化环氧树脂成膜剂的制备[J].吉林大学学报(理学版),2018,56(5):1273-1277.
作者姓名:马晓坤  冯旭  李峰  贾宏菲  杨春才
作者单位:吉林化工学院 化学与制药工程学院, 吉林 吉林 132022
摘    要:以环氧树脂为疏水基团, 聚乙二醇为亲水基团, 在三氟化硼乙醚作用下反应制备一种自乳化环氧树脂成膜剂, 并利用红外光谱、 扫描 电镜和激光粒度仪对其进行分析测试. 结果表明: 该成膜剂含有亲水的羟基和长链的环氧基团; 自乳化后的乳液粒度为70~150 nm; 该自乳化成膜剂稳定性良好, 其贮存稳定性可超过30 d; 离心3 h后的乳液仍保持稳定.

关 键 词:自乳化    环氧树脂    乳液    成膜剂  
收稿时间:2017-11-17

Preparation of Self-emulsifying Epoxy Resin Film-Forming Agent
MA Xiaokun,FENG Xu,LI Feng,JIA Hongfei,YANG Chuncai.Preparation of Self-emulsifying Epoxy Resin Film-Forming Agent[J].Journal of Jilin University: Sci Ed,2018,56(5):1273-1277.
Authors:MA Xiaokun  FENG Xu  LI Feng  JIA Hongfei  YANG Chuncai
Institution:School of Chemistry and Pharamaceutical Engineering, Jilin Institute of Chemical Technology, Jilin 132022, Jilin Province, China
Abstract:A self-emulsifying epoxy resin film\|forming agent wasprepared by using epoxy resin as hydrophobic group and polyethylene glycol as hydrophilic group under the action of boron trifluoride ethyl ether. Thefilm-forming agent was analyzed by infrared spectrum, scanning electron microscope and laser particle size analyzer. The results show that film-forming agent contains hydrophilic hydroxyl and long chain epoxy groups. And theparticle size of emulsion after self-emulsifying is 70—150 nm. The self-emulsifying film-forming agent has good stability, and its storage stability canbe more than 30 d. The emulsion can remain stable after centrifugationfor 3 h.
Keywords:self-emulsifying  epoxy resin  emulsion  film-forming agent
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