| H4SiW6Mo6O40／SiO2在H2O2催化氧化环己酮合成己二酸中的应用 |
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| 引用本文： | 杨水金,喻莉,王雨飞,杨赟,孙文兵.H4SiW6Mo6O40／SiO2在H2O2催化氧化环己酮合成己二酸中的应用[J].湖北大学学报(自然科学版),2013(1):123-127. |
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| 作者姓名： | 杨水金 喻莉 王雨飞 杨赟 孙文兵 |
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| 作者单位： | 湖北师范学院化学与环境工程学院;污染物分析与资源化技术湖北省重点实验室(湖北师范学院);湖北大学化学化工学院 |
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| 基金项目： | 湖北省教育厅重点科研基金(D20122205)资助 |
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| 摘 要： | 采用溶胶一凝胶法制备了二氧化硅负载硅钨钼酸催化剂．以二氧化硅负载硅钨钼酸（H4SiW6M06040／SiO2）为催化剂，30％H202为氧源，催化氧化环己酮合成己二酸．探讨H4SiW6Mo6O40／SiO2对氧化反应的催化活性，较系统地研究了二氧化硅负载硅钨钼酸用量、反应温度、H。02用量、反应时间等因素对产物收率的影响．实验表明：H4SiW6Mo6O40／SiO2是合成己二酸的良好催化剂；在n（环日酮）：n（H2O2）：n（H4SiW6Mo6O40／SiO2）=100：198：0．124，反应温度为110℃，反应时间3．5h的最佳条件下，己二酸的收率可达86．7％．
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| 关 键 词： | H4SiW6Mo6O40 SiO2 催化 环己酮 己二酸 |
Application of H4SiW6Mo6O40/SiO2 as catalyst in the oxidation of cyclohexanone to adipic acid by H2O2 |
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| YANG Shuijin,YU Li,WANG Yufei,YANG Yun,SUN Wenbing.Application of H4SiW6Mo6O40/SiO2 as catalyst in the oxidation of cyclohexanone to adipic acid by H2O2[J].Journal of Hubei University(Natural Science Edition),2013(1):123-127. |
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| Authors: | YANG Shuijin YU Li WANG Yufei YANG Yun SUN Wenbing |
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| Institution: | 1,2(1.College of Chemistry and Environmental Engineering,Hubei Normal University,Huangshi 435002,China;2.Hubei Key Laboratory of Pollutant Analysis & Reuse Technology(Hubei Normal University),Hubei Provincial Department of Education, Huangshi 435002,China;3.School of Chemistry and Chemical Engineering,Hubei University,Wuhan 430062,China) |
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| Abstract: | A new environmental friendly catalyst,H4SiW6Mo6O40/SiO2 was prepared by Sol-gel method. Using H4 SiW6 M06 O40/SiOz as catalyst, adipic acid was synthesized from the oxidation of cyclohexanone by 30% H2 02. Influences of dosage of H4 SiW6 M06 O40/SIO2, reaction temperature, volume of hydrogen peroxide and reaction time were also discussed. Experimental results were shown that.H4SiW6Mo6O40/SiO2 was a good catalyst for synthesis of adipic acid. When n（cyclohexene）：n（H2O2） ： n（H4SiW6Mo6O40/SiO2） = 100 ： 198 ： 0.124, reaction temperature was 110 ℃ and reaction time was 3. 5 h, under the optimum conditions, the yield of adipic acid was 86.7%. |
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| Keywords: | H4SiW6Mo6O40／SiO2 catalysis cyclohexanone adipic acid |
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