| 用对称性法讨论d轨道的能级分裂 |
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| 引用本文： | 陈华君,范淑文.用对称性法讨论d轨道的能级分裂[J].齐齐哈尔大学学报(自然科学版),1989(1). |
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| 作者姓名： | 陈华君 范淑文 |
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| 作者单位： | 齐齐哈尔师范学院
(陈华君)，齐齐哈尔轻工学院化工系(范淑文) |
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| 摘 要： | 本文根据对称点群的任何操作R作用于分子上时,分子变换成一个等价构型,选择具有代表性特征变换R作用于五个d轨道,通过变换情况建立简并轨道之间的联系,即可得到d轨道在外场中分裂的信息。
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| 关 键 词： | 本征函数 本征值 点群 对称操作 |
A Discussion on the Energy Grade Split of d Orbits by the Symmetric Methods |
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| Chen Huajun Fan Shuwen.A Discussion on the Energy Grade Split of d Orbits by the Symmetric Methods[J].Journal of Qiqihar University(Natural Science Edition),1989(1). |
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| Authors: | Chen Huajun Fan Shuwen |
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| Institution: | Chen Huajun Fan Shuwen
(Qiqihaer Teacher's College) (Qiqihaer Institute of Light Industry) |
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| Abstract: | According to the principle that when any operation R of a symmetrical point-group acts on a molecule, the molecule changes into one of its equivralent configurations, In this paper we try to set up the connections between the
degenerate orbits so as to obtain the split imformation of the orbits in the
ligand field by means of selecting some characteristic transformation R as
representative and making it operate on five d orbits. |
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| Keywords: | Eigenf unction Eigenvalnes Point group Symmetrical operation |
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