| 在ZSM－5催化剂上甲醇氨化合成甲胺的反应动力学 |
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| 引用本文： | 沈伟,陈幸幸,徐华龙,项一非. 在ZSM－5催化剂上甲醇氨化合成甲胺的反应动力学[J]. 复旦学报(自然科学版), 1996, 0(3) |
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| 作者姓名： | 沈伟 陈幸幸 徐华龙 项一非 |
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| 作者单位： | 复旦大学化学系 |
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| 摘 要： | 在微反－色谱装置上研究甲醇在ＨＺＳＭ－５和ＰＺＳＭ－５催比剂上氨化合成甲胺的反应动力学．结果表明，对于ＨＺＳＭ－５和ＰＺＳＭ－５催化剂，甲醇氨化对甲醇蒸汽压为一级反应．ＨＺＳＭ－５经Ｐ改性后降低了催化反应的活化能．从而使ＰＺＳＭ－５有更好的活性．
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| 关 键 词： | 甲醇；沸石；氨化；甲胺；ZSM－5；反应动力学 |
Study on the reaction kinetics of ZSM-5 zeolite catalyst for methylamines |
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| Shen Wei, Chen Xingxing, Xu Hualong, Xiang Yifei. Study on the reaction kinetics of ZSM-5 zeolite catalyst for methylamines[J]. Journal of Fudan University(Natural Science), 1996, 0(3) |
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| Authors: | Shen Wei Chen Xingxing Xu Hualong Xiang Yifei |
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| Affiliation: | Department of Chemistry |
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| Abstract: | he reaction kinetics of ammoniation of methanol over HZSM-5 and PZSM-5 catalyst has been studied. The results show that ammoniation of methanol is of first order in refer to methanol vapor pressure. Modification of HZSM-5 with P decreases the activation energy of the catalytic reaction,then PZSM-5 has a higher activity. |
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| Keywords: | ethanol zeolite ammoniation methylamines ZSM-5 reaction kinetics |
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