| 双头基多氟烷基两亲杯[4]芳烃的Langmuir-Blodgett膜 |
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| 引用本文： | 姜双双,朱珠,金传明.双头基多氟烷基两亲杯[4]芳烃的Langmuir-Blodgett膜[J].湖北师范学院学报(自然科学版),2014(1):68-72. |
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| 作者姓名： | 姜双双 朱珠 金传明 |
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| 作者单位： | 湖北师范学院化学化工学院,湖北黄石435002 |
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| 基金项目： | 湖北省高校优秀中青年科技创新团队项目（T2D1311） |
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| 摘 要： | 合成了双头基多氟烷基两亲杯4]芳烃化合物1和2,利用表面压一面积(π-A)等温线、压缩/扩张循环等温线与膜稳曲线研究了他们在空气/水相界面的成膜性能,并用紫外光谱和原子力显微镜对组装的LB膜进行了结构表征。结果表明:化合物1和2在空气/水相表面均能很好的形成稳定的Langmuir膜,取代基碳原子数的增加使得化合物2的Langmuir膜单分子面积增加,崩溃压相应减少,组装的LB膜均为H-聚集体,结构均匀,稳定性好。
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| 关 键 词： | 杯[]芳烃 LB膜 H-聚集体 原子力显微镜 |
Studies on langmuir-blodgett film of amphiphilic calix[4]arene derivatives containing polyfluoroalkanyl groups |
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| JIANG Shuang-shuang,ZHU Zhu,JIN Chuan-ming.Studies on langmuir-blodgett film of amphiphilic calix[4]arene derivatives containing polyfluoroalkanyl groups[J].Journal of Hubei Normal University(Natural Science),2014(1):68-72. |
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| Authors: | JIANG Shuang-shuang ZHU Zhu JIN Chuan-ming |
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| Institution: | (College of Chemistry and Chemical Engineering, Hubei Normal University, Huangshi 435002, China) |
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| Abstract: | Amphiphilic Calix4]arene Derivatives 1 and 2 Containing Polyfluoroalkanyl Groups were synthesized .Its Lang-muir-Blodgett （LB） film on air/water surface were characterized by π-A isotherms, the compress and outspread isotherms , the film stabilize isotherms, UV-Vis and FT-IR spectrum, atomic force microscope （AFM）.The results indicate that com-pounds 1 and 2 could form stable monolayer or multilayer film with H -aggregate on air/water surface.The average molecular areas of 2 is bigger and the collapse surface pressure is smaller than 1, because of the length of substituted group . |
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| Keywords: | calix[4]arene langmuir-blodgett film H-aggregate AFM |
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