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CTAB/正丁醇/正庚烷/水微乳体系稳定性研究
引用本文:赵国平,陈国辉. CTAB/正丁醇/正庚烷/水微乳体系稳定性研究[J]. 山东大学学报(理学版), 2007, 42(11): 19-22
作者姓名:赵国平  陈国辉
作者单位:中南大学,化学化工学院,湖南,长沙,410083;中南大学,化学化工学院,湖南,长沙,410083
摘    要:制备了十六烷基三甲基溴化铵(CTAB)/正丁醇/正庚烷/水体系拟三元相图;通过电导法确定了十六烷基三甲基溴化铵(CTAB)/正丁醇/正庚烷/水微乳体系结构;研究了温度、酸度对微乳体系稳定性的影响。结果表明,在较大的表面活性助剂与表面活性剂的质量比值范围内(w(乳化剂)=m(C4H9OH)/m(CTAB)),体系能在较大的组成范围内形成微乳区,该微乳区对温度变化不敏感。随着体系水相酸度的增加,微乳体系的含水量呈不规则变化。

关 键 词:CTAB  微乳液  电导率  温度
文章编号:1671-9352(2007)11-0019-04
收稿时间:2007-06-22

Stabilization of CTAB/C4H9OH/C7H16/H2O micro-emulsion system
ZHAO Guo-ping,CHEN Guo-hui. Stabilization of CTAB/C4H9OH/C7H16/H2O micro-emulsion system[J]. Journal of Shandong University, 2007, 42(11): 19-22
Authors:ZHAO Guo-ping  CHEN Guo-hui
Affiliation:Institute of Chemistry and Chemical Engineering, Central South of University, Changsha 410083, Hunan, China
Abstract:Phase diagrams of the pseudo-ternary -component of CTAB/C4H9OH/n-C7H16/H2O system were plotted by the dilution method. The structures of micro-emulsions in the system of CTAB/C4H9OH/n-C7H16/H2O were determined by conductance measurement. The effect of temperature and acidity on micro-emulsion was evaluated. The result indicates that micro-emulsion regions can be formed within larger composition variation of w(Emulsifier)=m(C4H9OH)/m(CTAB) value (the mass ratio of co-surface and surface). In addition, the micro-emulsion regions are insensitive to temperature change. With increasing aqueous acidity, the water content of the micro-emulsion system shows irregular changes.
Keywords:CTAB
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