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| 微波合成配位离子液体 | |
| 引用本文： | 赵地顺,鲍晓磊,闪俊杰,武 彤,王文荣. 微波合成配位离子液体[J]. 河北科技大学学报, 2010, 31(2): 128-131 |
| 作者姓名： | 赵地顺 鲍晓磊 闪俊杰 武 彤 王文荣 |
| 作者单位： | 1. 河北科技大学化学与制药工程学院,河北石家庄,050018 2. 开滦集团唐山中润煤化工有限公司,河北唐山,063000 3. 石药集团维生药业,石家庄,有限公司,河北石家庄,050035 |
| 摘 要： | 采用微波辐射加热法合成了一系列环境友好的配位离子液体(C4H9)4NX.C6H11NO,X=Cl-,Br-,Ac-。与热合成法相比,该方法合成配位离子液体(CILs)具有反应时间短、能耗低、无需加入有机溶剂等优点,通过IR,1H NMR对化合物结构进行了表征,测定了该系列CILs的电导率、pH值和溶解性等物化性质。 |
| 关 键 词： | 配位离子液体 绿色溶剂 微波辐射 |
| 收稿时间： | 2009-06-30 |
| 修稿时间： | 2009-10-19 |
Synthesis of coordinated ionic liquids under microwave irradiation |
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| ZHAO Di-shun,BAO Xiao-lei,SHAN Jun-jie,WU Tong and WANG Wen-rong. Synthesis of coordinated ionic liquids under microwave irradiation[J]. Journal of Hebei University of Science and Technology, 2010, 31(2): 128-131 | |
| Authors: | ZHAO Di-shun BAO Xiao-lei SHAN Jun-jie WU Tong WANG Wen-rong |
| Affiliation: | 1. College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang Hebei 050018, China; 2. Tangshan Zhongrun Coal Chemical Company Limited, Kailuan Group, Tangshan Hehei 063000, China;3. Weisheng Pharmaceutical(Shijiazhuang) Company Limited, CSPC, Shijiazhuang Hehei 050035, China) |
| Abstract: | A mild, efficient and eco-friendly procedure for the synthesis of a series novel ionic liquids-coordinated ionic liquids with formula （C4 H9 ）4 NX · C6 H11 NO （X= Cl- , Br- and Ac-） under microwave irradiation was investigated. The CILs were characterized by IR and 1 H NMR methods. The properties of this kind of CILs were investigated. |
| Keywords: | coordinated ionic liquids（CILs） green solvents microwave irradiation |
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