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Influence of graphene microstructures on electrochemical performance for supercapacitors
Authors:Youning Gong  Delong Li  Qiang Fu and Chunxu Pan
Institution:School of Physics and Technology, and MOE Key Laboratory of Artificial Micro- and Nano-structures, Wuhan University, Wuhan 430072, China;School of Physics and Technology, and MOE Key Laboratory of Artificial Micro- and Nano-structures, Wuhan University, Wuhan 430073, China;School of Physics and Technology, and MOE Key Laboratory of Artificial Micro- and Nano-structures, Wuhan University, Wuhan 430074, China;School of Physics and Technology, and MOE Key Laboratory of Artificial Micro- and Nano-structures, Wuhan University, Wuhan 430075, China
Abstract:The influence of variant graphenes on electrochemical performance for supercapacitors was studied comparatively and systematically by using SEM, FTIR and Raman spectroscopy, cyclic voltammetry (CV), galvanostatic charge/discharge and electrochemical impedance spectroscopy (EIS). The results revealed that: 1) the nitrogen-doped graphene (N-G) electrode exhibited the highest specific capacitance at the same voltage scan rate; 2) the specific capacitance of the N-G reached up to 243.5 F/g at 1 A/g, while regular graphite oxide (GO) was 43.5 F/g and reduced graphene oxide (rGO) was 67.9 F/g; 3) N-G exhibited the best supercapacitance performance and the superior electrochemical properties, which made it an ideal electrode material for supercapacitors.
Keywords:Graphene  Nitrogen doping  Microstructure  Supercapacitor
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