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Extraction kinetics of lanthanum with purified Cyanex 923 from nitrate medium
Authors:Tong?Hui  Email author" target="_blank">Li?De-qianEmail author  Wang?Yi-ge  Lei?Jia-heng
Institution:(1) School of Natural Sciences, Wuhan University of Technology, 430070 Wuhan, Hubei, China;(2) Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 130022 Changchun, Jilin, China
Abstract:Solvent extraction kinetics of lanthanum with purified Cyanex 923 in heptane from nitrate medium was investigated by using a constant interfacial cell with laminar flow at 303 K. The effects of stirring speed, temperature and specific interface on the extraction rate were studied. The experimental results showed that the extraction apparent activation energy was 32.0 kJ\5mol -1 and the extraction process was controlled by both chemical reaction and diffusion. The extraction rates were measured at different chemical compositions by varying ionic strength, pH value and the concentration of purified Cyanex 923. The initial extraction rate equation was obtained.
Keywords:lanthanum  Cyanex 923  solvent extraction kinetics
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