| Preparation of (R)-and (S)-2-Allyl-1,3,2-Dinaphtho(α,β)[d.f]dioxaborepin and Their Reactions with Aldehydes |
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| 引用本文： | Liu De-jun,Shan Zi-xing ,Wang Guo-ping,Qin Jin-gui College of Chemistry and Molecular Sciences,Wuhan University,Wuhan 430072,Hubei,China. Preparation of (R)-and (S)-2-Allyl-1,3,2-Dinaphtho(α,β)[d.f]dioxaborepin and Their Reactions with Aldehydes[J]. 武汉大学学报:自然科学英文版, 2003, 8(4) |
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| 作者姓名： | Liu De-jun Shan Zi-xing Wang Guo-ping Qin Jin-gui College of Chemistry and Molecular Sciences Wuhan University Wuhan 430072 Hubei China |
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| 作者单位： | Liu De-jun，Shan Zi-xing ，Wang Guo-ping，Qin Jin-gui College of Chemistry and Molecular Sciences，Wuhan University，Wuhan 430072，Hubei，China |
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| 基金项目： | SupportedbytheNationalNaturalScienceFoundationofChina (2 9972 0 33) |
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| 摘 要： | 0 IntroductionEnantiopure 1,1′ bi 2 naphtholspossessingC2 chiralityhaveprovedtobeversatilechiralauxiliariesinanumberofasym metricreactions[1 |6] .Althoughsomeboroncompoundsofthemhavebeenprepared[7 1 6] ,chemistryoftheirallylboranederivativeshasneverbeenreported .Toexplorepossibilityofapplyingseven memberedcyclicchrialallylboronateesterstoasymmetricsynthesisofchiralβ alkenylalcohols,whichareimportantintermediateinthepreparationofopticallyactivenaturalproducts,werecentlyat temptedtosynthesi…
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| 关 键 词： | 1 1′-bi-2-naphthyl allylboronate |
Preparation of (R)- and (S)-2-Allyl-1,3,2-Dinaphtho(α,β)[d.f]dioxaborepin and Their Reactions with Aldehydes |
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| Liu De-jun,Shan Zi-xing,Wang Guo-ping,Qin Jin-gui. Preparation of (R)- and (S)-2-Allyl-1,3,2-Dinaphtho(α,β)[d.f]dioxaborepin and Their Reactions with Aldehydes[J]. Wuhan University Journal of Natural Sciences, 2003, 8(4) |
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| Authors: | Liu De-jun Shan Zi-xing Wang Guo-ping Qin Jin-gui |
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| Abstract: | |
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| Keywords: | 1 1'-bi-2-naphthyl allylboronate preparation asymmetric allylation |
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