Supramolecular Organization of Porphyrin and Phthalocyanine by Complementary Coordination |
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| Authors: | Yoshiaki Kobuke Masakuni Fujita Toshimasa Sugimura Akiharu Satake |
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| Institution: | [1]Institute of Advanced Energy Kyoto University [2]Graduate School of Materials Science [3]Nara Institute of Science and Technology [4]Japan |
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| Abstract: | 1 Results We have already established a methodology of supramolecular organization of porphyrin and phthalocyanine by complementary coordination of the imidazolyl substituent to their metal centers.Since the stability constants reached a range of 1011 to 1012 M-1 in nonpolar solvents,it allowed construction of stable structures such as special pair of photosynthetic reaction center and light-harvesting antenna complex of photosynthetic bacteria.Here,we report one-dimensional array of porphyrin for the d... |
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| Keywords: | supramolecular porphyin phthalocyanine |
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