| 稀土高氯酸盐甘氨酸咪唑三元配合物的热分析 |
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| 引用本文： | 刘向荣. 稀土高氯酸盐甘氨酸咪唑三元配合物的热分析[J]. 西安科技大学学报, 2001, 21(4): 352-355 |
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| 作者姓名： | 刘向荣 |
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| 作者单位： | 西安科技学院,材料工程系, |
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| 基金项目： | 国家自然科学基金项目(项目编号:29271028;29471023) |
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| 摘 要： | 采用TG-DTG,DSC对9种稀土高氯酸盐甘氨酸咪唑三元配合物的热分解过程进行了研究.比较了配合物的热稳定性;利用Kissinger公式计算了配合物的表观分解活化能;从DSC分析得到了配合物的脱水焓及分解焓,发现稀土配合物的表观分解活化能、配合物的脱水焓及分解焓呈现一定的规律性.
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| 关 键 词： | 稀土高氯酸盐 甘氨酸 咪唑 配合物 热分析 |
| 文章编号： | 1671-1912(2001)04-0352-04 |
| 修稿时间： | 2001-04-28 |
Thermal analysis of ternary complexes of rare earth perchlorate with glycine and imidazole |
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| LIU Xiang rong. Thermal analysis of ternary complexes of rare earth perchlorate with glycine and imidazole[J]. JOurnal of XI’an University of Science and Technology, 2001, 21(4): 352-355 |
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| Authors: | LIU Xiang rong |
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| Abstract: | The thermal decomposition process of nine ternary complexes of rare earth perchlorate with glycine and imidazole were studied by use of TG DTG. Their apparent activation energies were calculated with Kissing method. The enthalpy values of dehydration and thermal decomposition were determined by DSC. Some rules of the thermal behaviors for these complexes have been founded. |
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| Keywords: | rare earth perchlorate glycine imidazole complex thermal analysis |
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