Spontaneous transformation of C60Br24 to C60 in solvents |
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| Authors: | Liu Ying Chen Yuanyin Sheng Rongsheng Zhang Xungao |
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| Affiliation: | (1) College of Chemistry, Wuhan University, 430072 Wuhan, China;(2) College of Analysis and Measurement Science, Wuhan University, 430072 Wuhan, China |
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| Abstract: | It was found that C60Br24 transforms to C60 spontaneously in some solvents. The intermediate, C60Br8, can be separated in some cases. When the bromine trap, phenol, was added,p-bromophenol and other brominated product were obtained and identified. The influences of time, the kind of solvent, etc were investigated. Possible mechanism was suggested. Supported by the National Natural Science Foundation of China Liu Ying: born in 1969, Ph. D |
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| Keywords: | C60Br24 dissociation C60Br8 C60 |
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