| 一维Z型链状配合物[Cd（bipy）Cl2]n的水热合成及其晶体结构研究 |
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| 引用本文： | 姜娈.一维Z型链状配合物[Cd（bipy）Cl2]n的水热合成及其晶体结构研究[J].宝鸡文理学院学报(自然科学版),2011,31(2):40-42. |
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| 作者姓名： | 姜娈 |
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| 作者单位： | 宝鸡文理学院化学化工系,陕西宝鸡,721013 |
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| 基金项目： | 陕西省重点实验室项目(09JS068); 宝鸡文理学院科研资助项目(ZK1020) |
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| 摘 要： | 目的研究配位聚合物Cd(bipy)Cl2]n晶体结构。方法以CdCl2和2,2’-联吡啶(2,2’-bipyridine,简称bipy)为原料,采用水热法合成并利用元素分析、X射线单晶衍射对其结构进行表征。结果研究结果表明,该配合物属于单斜晶系,C2/c空间群,a=1.754 3(5)nm,b=0.930 1(5)nm,c=0.716 5(5)nm,β=110.929(5)°,V=1.092 0(10)nm3,Z=4,Dc=2.065 g/cm3,μ=2.453mm-1,F(000)=656,R1=0.022 6,wR2=0.044 7。结论该化合物呈一维Z型链状结构。
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| 关 键 词： | 2 2’-联吡啶 镉 水热合成 晶体结构 |
Hydrothermal synthesis of a novelone-dimensional zigzag chain coordination polymer [Cd(bipy)Cl_2]_n and its crystal structure |
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| JIANG Luan.Hydrothermal synthesis of a novelone-dimensional zigzag chain coordination polymer [Cd(bipy)Cl_2]_n and its crystal structure[J].Journal of Baoji College of Arts and Science(Natural Science Edition),2011,31(2):40-42. |
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| Authors: | JIANG Luan |
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| Institution: | JIANG Luan(Dept.Chem.& Chem.Eng.,Baoji Univ.Arts & Sci.,Baoji 721013,Shaanxi,China) |
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| Abstract: | Aim To research the crystal structure of coordination polymer Cd(bipy)Cl2]n.Methods A novel one-dimensional zigzag chain coordination polymer Cd(bipy)Cl2]n was synthesized by hydrothermal reaction with CdCl2 and 2,2'-bipyridine(bipy) as raw materials.The structure was characterized with elemental analysis,single crystal X-ray diffraction analysis.Results The experimental results show that the title compound crystallizes in monoclinic space group C2/c,with a = 1.754 3(5) nm,b= 0.930 1(5) nm,c= 0.716 5(5) n... |
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| Keywords: | 2 2'-bipyridine cadmium hydrothermal synthesis crystal structure |
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