| 季铵碱化酞菁钴的合成及其脱硫醇动力学 |
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| 引用本文： | 夏道宏,苏贻勋,钱家磷. 季铵碱化酞菁钴的合成及其脱硫醇动力学[J]. 中国石油大学学报(自然科学版), 1994, 0(5) |
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| 作者姓名： | 夏道宏 苏贻勋 钱家磷 |
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| 作者单位： | 石油大学炼制系，石油大学化工学部 |
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| 摘 要： | 首次合成了一种在同一分子内兼有氧化催化中心和碱中心的新型轻质油品脱硫醇催化剂季锭碱化酞菁钴。动力学实验结果表明，其分子内的氧化催化中心与碱中心在催化硫醇氧化反应中具有协同作用，并表现出比磺化酞菁钴好的催化活性。
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| 关 键 词： | 脱硫醇催化剂；季铵碱化酞菁钻；硫醇氧化 |
SYNTHESIS OF COBALT QUARTERNAKY AMINE HYDROXID-SUBSTITUDED PHTHALOCYANINE AND ITS KINETICS CHARACTEKISTICS IN L10HT OIL SWEETENING |
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| Xia Daohong,Su Yixun,Qian Jialin. SYNTHESIS OF COBALT QUARTERNAKY AMINE HYDROXID-SUBSTITUDED PHTHALOCYANINE AND ITS KINETICS CHARACTEKISTICS IN L10HT OIL SWEETENING[J]. Journal of China University of Petroleum (Edition of Natural Sciences), 1994, 0(5) |
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| Authors: | Xia Daohong Su Yixun Qian Jialin |
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| Abstract: | A new high oil sweetening catalyst cobalt quarternary amine hydroxid-substitutedphthalocyanine (CoQAHPc)which including both oxidation-catalytic site and basic siteintramolecularly has been firstly synthesized,The experimental results show that the twoactive sites of the new catalyst have concert action on the oxidation of n-butyl mercaptan,andits catalytic activity is better than that of cobalt sulfonated phthalocyanine. |
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| Keywords: | Dethio:Cobal quarternary amiane gydroxide-substituted phthalocyanine:Thiol oxidiation |
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